A rough timeline of photographic technique history, as I’ve read it so far, to fix it in my own brain as much as anything. If you’re up for a bit of fixating, read on.
Lifted once again from Wikipedia: ‘The first permanent photograph was made in 1826 by a French inventor, Joseph Nicéphore Niépce, building on a discovery by Johann Heinrich Schultz (1724): that a silver and chalk mixture darkens under exposure to light. Niépce and Louis Daguerre refined this process. Daguerre discovered that exposing the silver first to iodine vapor, before exposure to light, and then to mercury fumes after the photograph was taken, could form a latent image; bathing the plate in a salt bath then fixes the image. These ideas led to the famous daguerreotype.’
These were announced in 1839, and in the same year, William Henry Fox Talbot finds a way of coating paper with silver iodide and developing it in ‘a gallo-nitrate of silver solution’ (before this, he used to use tiny pictures treated with wax, which he could use as negatives and which took very long exposure times). The new type were called ‘Calotypes’.
It looks like various people were working on improving exposure times and improving the photographic process at the same time, and patenting everything they could. It must have been really exciting; the first time you capture good images on a surface, without your poor subject having to sit as still as possible for very long amounts of time! And of course, amazing in itself.
After this came the collodion process from 1848, where a glass plate was coated with a combination of potassium iodide, and colloidon, a transparent sticky material. The plate was bathed in silver nitrate to make it sensitive to light and then exposed. Prints could be made on albumen paper, and I believe this process wasn’t patented by the ‘inventor’ (Archer) so everyone got to use it for free.
Something else called a Verreotype also seemed to supercede the daguerreotype, being faster and more usable in poor light, and less prone to fading.
But the next big deal was the gelatine process from 1871, introduced by R.L. Maddox. Again lifted from wikipedia: ‘A suspension of silver salts in gelatin is coated onto acetate film or fiber-based or resin coated paper and allowed to dry (hence the term dry plate). These materials remain stable for months and years unlike the ‘wet plate’ materials that preceded them.
This is basically what is used in Black and white films and papers today apparently. More detail (same source): ‘When small crystals (called grains) of silver salts such as silver bromide and silver chloride are exposed to light, a few atoms of free metallic silver are liberated. These free silver atoms form the latent image. This latent image is relatively stable and will persist for some months without degradation provided the film is kept dark and cool.
Films are developed using solutions that reduce the free silver atoms. An ‘amplification’ of the latent image occurs as the silver salts near the free silver atom are also reduced to metallic silver. The strength, temperature and time for which the developer is allowed to act allow the photographer to control the contrast of the final image. The development is then stopped by neutralizing the developer in a second bath.
Once development is complete, the undeveloped silver salts must be removed by fixing in sodium thiosulphate or ammonium thiosulphate, and then the film or paper must be washed in clean water. The final image consists of metallic silver embedded in the gelatin coating.’
That appears to be the basics of the process, but it looks like lots of different processes came from those early intensely creative periods of discovery, and I would love to think that a hardy band of enthusiasts or artists or both will continue to use them creatively and successfully (although how long the materials to do so will last is anyone’s guess). Also, there are some other processes out there also.